My best guess is this man, F. LeBaron Goodwin, of Co. "A", 27th Alabama. Promoted Captain [April 1863] to rank February 17, 1863. Assigned to duty as enrolling officer of Walker County, Alabama, August 22, 1863. Captured at Tuscaloosa, Alabama, on April 3, 1865, and paroled the following day.

Goodwin may have been on temporary detail as enrolling officer in the area prior to 1863; I don't see specific records about him in 1862. There's also a John Goodwin, Capt. of Co. "E", 2nd Alabama Infantry. He served as an enrolling officer at Tuscumbia.