This isn't exactly what you are looking for but it might help somewhat. It is a listing of Kentucky State Guard units by county with the officers listed. Most of these units enlisted together and became companies. For example, the Beauregards from Princeton, Caldwell County, became Company C, 3rd Kentucky Infantry. The Lyon County Company became Company F, 3rd Kentucky Infantry, then Lyon's/Cobb's Battery.
Hopefully it will give you a starting point.

Todd