Charlotte Rooks' first husband was Samuel Lafayette Rooks. There is a lot of info about him on the web. I believe he died up north in a prison camp during the war.
1870 Census Laurens County, Jacks Township,taken 8Aug 1870:
John G. Lipford 25 years Occ: farmer
Charlotte E 31 years Occ: keeping house
Lila Rooks 15 at home
Willie Rooks 13 at school
Elizabeth Rooks 10 at school
Virda Rooks 9
Rawanna Rooks 6
John Lipford 3
Charles Lipford 1
He valued his land at $2,000 and personal belongings $450.