O.R. Pages 95-103 Series 4 - Volume 3
I found a very detailed Confederate report of the total number of men in Confederate service. It only includes half of the states; Georgia, South Carolina, North Carolina, Virginia, Alabama, and Mississippi.
This has the most detail by ages, type of service, exempts, ect. that I have seen so far.
Total number by January 1864- 566,456.
http://cdl.library.cornell.edu/cgi-bin/moa/pageviewer?frames=1&coll=moa&view=50&root=%2Fmoa%2Fwaro%2Fwaro0129%2F&tif=00107.TIF&cite=http%3A%2F%2Fcdl.library.cornell.edu%2Fcgi-bin%2Fmoa%2Fmoa-cgi%3Fnotisid%3DANU4519-0129
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David Upton