I've done quite a bit of annotating through the Texas officers files. You might find other good sources by searching for "san antonio texas" and "powder" or "gunpowder" or perhaps Laredo or Brownsville or Mexico. One of the problems is that the place and the topic must appear on the same page for them to pull up together, and sometimes that doesn't happen in longer correspondence. If you have access to this database, just play around a little with the search terms.
Vicki Betts