To answer your question it seems like I have read that NC troops did use some of the rubber buttons and I have seen a kepi with a rubber button for the chin strap but it was not a military button. but I can't remember where. However, eyeballing the ground in Portsmouth Va. around the previous Gosport SY area, there are many very early rubber buttons with Goodyear B/Ms found. That area was camps from both sides at different periods of the war. However, rubber buttons were not being manufactured by the Confederacy and when the pre-war supply was used up, something else was used.