Here's one member of the 5th Division that I was able to find:

Thomas Thurman, Lt. Col., 5th Division Missouri State Guard

M322: Compiled Service Records of Confederate Soldiers Who Served in Organizations from the State of Missouri

See also:

http://www.columbiatribune.com/news/local/years-ago-former-state-guard-officers-captured-near-jefferson-city/article_5c980a42-7449-55fc-942b-19e772394626.html