No battalion existed until December 1862 when the second company organized. Members of both companies came from different regiments of S. A. M. Wood's Brigade. The brigade included three Alabama regiments (16th, 33rd and 45th), so most members were Alabamians. Officers included Major A T Hawkins from Huntsville AL, Capt John H Coleman, 1st Lieut Daniel Coleman and 2nd Lieut Richard V Coleman of Athens AL, 2nd Lieut Harry Bethea of Montgomery AL and 2nd Lieut Andrew Brown from Florence AL. I'm not certain all of these officers were from Mississippi, but some were: 1st Lieut. T M Steger, 2nd Lieuts Harry Vasser, P B Andrews and B F Little.
Don't know why the War Department gave this battalion a Mississippi designation.